Generally speaking, a number [tex]x[/tex] coprime to [tex]n[/tex] will be a primitive root of [tex]n[/tex] if we have [tex]x^n\equiv x\mod{n}[/tex], or [tex]x^{n-1}\equiv1\mod{n}[/tex]. In other words, if [tex]x[/tex] is of order [tex]n-1[/tex] modulo [tex]n[/tex], then [tex]x[/tex] is a primitive root of [tex]n[/tex].
Since none of these numbers has order 19, it follows that 20 does not have any primitive roots.